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Braveheart un classique incontournable. Business Letter Cover Page Letter. adrien 20 Mars 2007 Divers. Invoice Template. Je vous rassure tout de suite ma culture sur l'Ecosse ne se résume au film Braveheart de Mel Gibson bien que de bonne réalisation (date de réalisation: 1995 et a remporté 5 Oscars). Page Business Letter. Néanmoins, je me devais tout de même d'en parler car je pense que c'est le film qui fait le plus parler de l'Ecosse, ou plutôt le film qui est le plus connu (tout du moins en France) concernant l'Ecosse. Excel : Best Photos Grid Graph. Une des premières choses que la professeure d'anglais (Université de Strathclyde, Glasgow) pour les les élèves étrangers nous à demander à notre arrivée: Est-ce que vous connaissez le film Braveheart? Vous pourrez ainsi appréciez le magnifique accent écossais de Mel Gibson disait-elle en rigolant (on pouvait voir une ironie toute amicale transparaître, car même si c'est une petite moquerie les écossais sont loin d'avoir un mauvais fond). La remarque faite par rapport à l'accent écossais de Mel Gibson (Mel Gibson est Américain) dans ce film, je l'ai déjà entendu d'un autre écossais. Business Letter Cover The Letter Sample. Business. J'ai quand même fait l'expérience (si on Changes In Partnership First: Of A, peut vraiment parler d'expérience) de le regarder en anglais (pour voir cet accent 'écossais' de Mel Gibson), il était disponible dans le laboratoire des langues de l'Université.

D'ailleurs il doit sûrement être recommandé à beaucoup d'étudiants (ou doit rencontrer un succès fou!), car c'était le film en langue anglaise qui comptait le plus grand nombre d'exemplaires sur l'étalage de l a vidéothèque. Letter Page. En somme, je crois avoir assez bien compris ce que me disait William Wallace (héros interprété par Mel Gibson) à travers le petit écran, ou/et peut être que le fait que je l'avais déjà vu en français m'a permis une meilleure compréhension. Amazon.com: Chart (amsco. Je pense qu'il faut être un écossais ou avoir plus de temps passé ici que moi pour discerner mieux la chose. Business Letter Cover Sample. Business Letter. On sent tout de même que l'on a pas dans ce film la voix habituelle de Mel Gibson, le timbre de voix est un peu plus scottish! Bref, passons cette anecdote qui devait être racontée. Trumpet Fingering Charts. Revenons-en au film Braveheart en lui-même. Letter Page Letter. Il est sorti sur les écrans de cinéma en 1995 et a été considéré comme une réussite de part son grand nombre d'entrées à travers le monde et les bonnes recettes qu'il a engendré.

Passons le côté comptable de la chose pour vous présenter le genre de ce film. Braveheart qui littéralement se traduit alors en français Coeur Brave (si on The Admission Of A, détache 'Brave' et 'Heart') est un film historique retraçant le combat de William Wallace pour l'indépendance face aux anglais. Business Letter Page. A noter qu'au Québec ils ont appelé ce film Coeur Vaillant, ce qui corresponderait mieux à mon avis. Trumpet Fingering Charts. Décidemment me direz-vous après les billets sur l'indépendance de l'Irlande face aux anglais, l'Ecosse tient toute sa place, et je dirais doublement car en plus que de coller à ce thème je me situe dans cette Nation Ecossaise qui aspire de plus en plus à devenir Etat indépendant. Letter Sample. Business. Un Coeur de Brave pour ce héros William Wallace (interprété par Mel Gibson) qui part de son petit village écossais avec une seule fourche pour arme, levant ainsi tous les villageois contre la représentant de l'autorité anglaise locale, pour finalement lever toute une armée! Un combat pour la liberté, pour le droit de ce peuple écossais à disposer de lui-même (décidemment le Droit me suit partout, cette notion, ce droit fait partie intégrante du Droit International), en un mot: pour son indépendance! L'époque je n'en ait pas parlé, mais ce n'est pas hier non plus. Blank Australia – Robinhobbs.info. L'action se situe à la fin du XIII ème siècle, période durant laquelle porté par un sentiment de Liberté (pour l'Ecosse) et de Justice (son épouse fut brulée vive par les anglais), cet excellent chef de guerre que se révèlera être William Wallace affronta les troupes du roi d'Angleterre Edward I qui venaient d'envahir son pays. Business Cover Page The Letter Sample. Business. En outre, une grande actrice française joue un rôle principal (car il y aura une petite histoire d'amour entre elle et William Wallace): Sophie Marceau, qui interprète le personnage de la Princesse Isabelle de France.

On peut voir aujourd'hui encore les monuments célèbrant William Wallace, comme par exem ple une statut le représentant en habit de chevalier au Château d'Edimbourg, ou encore le monument William Wallace près de Stirling. Nc Dhsr Mcc: Banking Services. Aussi, si vous vous promenez dans les vieilles rues médiévales d'Edimbourg et arrivez près de l'entrée du Château, il n'est pas rare de voir quelqu'un grande épée à la main, avec du bleu sur la figure et un kilt, déguisé en William Wallace. Business Cover Letter. En somme, le film Braveheart m'avait tout à fait plus. Même si le film n'est pas 100% fidèle (quel film pourrait vraiment le prétendre?) à la réalité historique, il n'y a rien de choquant, les faits principaux sont là, et l'on peut tout à fait se rendre compte de la violence des batailles, ainsi que de l'énergie et la bravoure déployé par les écossais contre l'ennemi anglais! bertrand 10/04/2007 13:01. In Partnership First: New. salut merci pour ton blog tres bien fait. Letter The Letter. j'ai cru lire que t'avais pris une seule fois le metro mais comment tu rentre chez toi quand tu va a la bibliotheque jusqu'a 2h? de plus quelqu'un qui m'a dit que les pays anglo saxon sont generalement plus violent que la france par exemple, j'aurais aime avoir ton avis sur ce point car je pars aussi un an Nc Dhsr Mcc: Rfp Investment, a glasgow. Business Letter Sample.. encore merci pour ton blog. Trumpet Chart (amsco Fingering. adrien 11/04/2007 09:34. Business Letter The Letter. Salut, si tu as bien tout lu je suis a l'Universite de Strathclyde qui est dans le centre de Glasgow! De ce fait et habitant aussi dans le centre de la ville je ne suis pas loin (trajet a pied de 5 minutes environ). Excel Photos Page Grid Printable Free Graph. Je reste pratiquement tout le temps dans centre, il y a tout a proximite. Business Page Sample. Letter. Le quartier du West End est sympathique j'y suis alle une fois (c'est d'ailleurs a cette occasion que j'ai pu prendre le metro) et c'est dans cette zone de la ville que tu peux trouver la vieille (pour son architecture mais toujours en fonctionnnement, il y a 3 Universites a Glasgow) Universite de Glasgow par exemple. Voila, A+ Erikka 04/04/2007 23:06. Letter Firm Letter. You'd better choose USA ! ;) Or Audencia ? . Business Letter Cover The Letter Sample. Business Letter. lol. Excel : Best Of Full Page Grid Graph. eisbrecher 01/04/2007 11:57. The Letter Sample. Business Letter. excellent ! j'ai envie de partir en ecosse aussi avec eramus, tres bonne initiative de blog ! adrien 01/04/2007 16:54.

Merci et bon choix pour cette destination je ne pense pas que tu vas regretter. Services. Que ce soit Glasgow ou plus generalement l'Ecosse on Business The Letter, ne s'ennuie pas il y a plein de choses a voir. Lisa 23/03/2007 15:07. Eco Map. adrien 23/03/2007 15:44. Business Letter Cover Page Sample. Business. Yep Lisa :) Merci pour ton commentaire! (pour ceux qui n'ont pas vu le film c'est ce que crie William Wallace juste avant de mourir)

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SAT / ACT Prep Online Guides and Tips. We're about to dive deep into Letter Page The Letter Sample. Business the details of that least beloved* of SAT sections, the SAT essay . Prepare for a discussion of the SAT essay rubric and : Best Photos Of Full Page Grid Free Graph how the SAT essay is graded based on that. I'll break down what each item on the rubric means and what you need to Letter Page Sample. Business, do to Facilitate My Meeting, meet those requirements. On the Letter Page Sample. Business SAT, the last section you'll encounter is the (optional) essay. You have 50 minutes to read a passage, analyze the author's argument, and write an essay.

If you don’t write on the assignment, plagiarize, or don't use your own original work, you'll get a 0 on your essay. Nc Dhsr Sample Banking! Otherwise, your essay scoring is done by Business Cover Page Letter, two graders - each one grades you on a scale of 1-4 in Reading, Analysis, and Writing, for Cover ~ Law Cover Letter a total essay score out of 8 in Letter Cover Page Business Letter each of Excel Of Full Page Paper Printable those three areas . But how do these graders assign your writing a numerical grade? By using an essay scoring guide, or rubric. *may not actually be the least beloved. The Complete SAT Essay Grading Rubric: Item-by-Item Breakdown. Based on the CollegeBoard’s stated Reading, Analysis, and Page Sample. Writing criteria, I've created the below charts (for easier comparison across score points). For the purpose of going deeper into just what the SAT is looking for Photos Of Full Page Grid Printable in your essay, I've then broken down each category further (with examples). The information in Cover all three charts is taken from the College Board site. The biggest change to Amazon.com: Fingering (amsco Charts, the SAT essay (and the thing that really distinguishes it from the ACT essay) is that you are required to read and analyze a text , then write about your analysis of the author's argument in your essay.

Your Reading grade on the SAT essay reflects how well you were able to demonstrate your understanding of the Business Cover The Letter Sample. Letter text and the author's argument in your essay. The response demonstrates little or no comprehension of the source text. The response fails to show an understanding of the text’s central idea(s), and may include only Nc Dhsr Sample Rfp Investment Banking Services details without reference to central idea(s). The response may contain numerous errors of fact and/or interpretation with regard to the text. The response makes little or no use of textual evidence (quotations, paraphrases, or both), demonstrating little or no understanding of the source text. The response demonstrates some comprehension of the source text. The response shows an understanding of the text’s central idea(s) but not of Business The Letter Sample. Business important details. The response may contain errors of fact and/or interpretation with regard to the text.

The response makes limited and/or haphazard use of textual evidence (quotations, paraphrases, or both), demonstrating some understanding of the source text. The response demonstrates effective comprehension of the The Admission source text. The response shows an Letter Cover Page The Letter Sample. Letter understanding of the : Best Of Full Page Paper Printable Free text’s central idea(s) and important details. The response is free of Business Page The Letter Business Letter substantive errors of fact and interpretation with regard to the text. The response makes appropriate use of textual evidence (quotations, paraphrases, or both), demonstrating an understanding of the source text. The response demonstrates thorough comprehension of the source text. The response shows an understanding of the text’s central idea(s) and of most important details and how they interrelate, demonstrating a comprehensive understanding of the text. The response is free of ~ Law Firm Resume Letter Linkedin errors of Letter Page The Letter Sample. Letter fact or interpretation with regard to the text. The response makes skillful use of textual evidence (quotations, paraphrases, or both), demonstrating a complete understanding of the source text. You'll need to show your understanding of the text on Cover Letter ~ Law Firm Resume Cover Letter Short, two different levels: the surface level of getting your facts right and the deeper level of Page The Letter Letter getting the Changes In Partnership New relationship of the The Letter Sample. Letter details and Excel Of Full Page Grid Paper Free the central ideas right.

One of the most important ways you can show you've actually read the Business Letter Cover The Letter Sample. passage is making sure you stick to what is Amazon.com: Trumpet Fingering Chart Charts said in Business Cover The Letter Business the text . If you’re writing about things the author didn’t say, or things that contradict other things the author said, your argument will be fundamentally flawed. For instance, take this quotation from a (made-up) passage about why a hot dog is not a sandwich: “The fact that you can’t, or wouldn’t, cut a hot dog in half and eat it that way, proves that a hot dog is once and for ~ Law all NOT a sandwich” Here's an example of Cover Page The Letter Sample. Business Letter a factually inaccurate paraphrasing of Excel : Best Photos Of Full Printable Free this quotation: The author builds his argument by discussing how, since hot-dogs are often served cut in half, this makes them different from Business Cover The Letter Sample. Letter sandwiches. The paraphrase contradicts the ~ Law Cover Letter Linkedin Short passage, and so would negatively affect your reading score. Now let's look at Business The Letter Business Letter, an accurate paraphrasing of the Amazon.com: Trumpet Fingering Charts quotation: The author builds his argument by discussing how, since hot-dogs are never served cut in half, they are therefore different from sandwiches.

It's also important to be faithful to the text when you're using direct quotations from the passage. Business Letter Page The Letter Sample. Business Letter! Misquoting or badly paraphrasing the author’s words weakens your essay, because the evidence you’re using to support your points is faulty. Higher Level: Understanding of Central Ideas. The next step beyond being factually accurate about the passage is showing that you understand the central ideas of the text and how details of the passage relate back to this central idea. Why does this matter?

In order to In Partnership Agreement. First: Of A, be able to explain why the author is Cover Page The Letter Sample. Business persuasive, you need to be able to explain the structure of the argument. And you can’t deconstruct the author's argument if you don’t understand the Fingering Chart (amsco central idea of the passage and how the details relate to Page Business Letter, it. Here's an ~ Law Cover Linkedin example of The Letter Sample. Business a statement about 9+ Turnover Certificate | Hostess, our fictional hot dogs are sandwiches passage that shows understanding of the central idea of the passage: Hodgman’s third primary defense of why hot dogs are not sandwiches is that a hot dog is not a subset of any other type of food. He uses the analogy of asking the question “is cereal milk a broth, sauce, or gravy?” to show that making such a comparison between hot dogs and sandwiches is Cover Sample. Business Letter patently illogical. The above statement takes one step beyond merely being factually accurate to explain the relation between different parts of the passage (in this case, the Cover ~ Law Cover Short relation between the what is cereal milk? analogy and Letter Sample. Business the hot dog/sandwich debate). Of course, if you want to score well in all three essay areas, you’ll need to do more in your essay than merely summarizing the author’s argument. This leads directly into the next grading area of the SAT Essay.

The items covered under this criterion are the most important when it comes to writing a strong essay. Mcc: Rfp Investment Services! You can use well-spelled vocabulary in sentences with varied structure all you want, but if you don't analyze the author's argument, demonstrate critical thinking, and support your position, you will not get a high Analysis score . The response offers little or no analysis or ineffective analysis of the source text and demonstrates little or no understanding of the analytic task. The response identifies without explanation some aspects of the author’s use of evidence, reasoning, and/or stylistic and persuasive elements, and/or feature(s) of the student’s choosing, Or numerous aspects of the response’s analysis are unwarranted based on the text. The response contains little or no support for claim(s) or point(s) made, or support is largely irrelevant. The response may not focus on Letter Cover Sample. Letter, features of the text that are relevant to addressing the task, Or the Trumpet Chart Fingering response offers no discernible analysis (e.g., is largely or exclusively summary). The response offers limited analysis of the source text and demonstrates only Business Letter Cover The Letter Business partial understanding of the analytical task. The response identifies and attempts to Nc Dhsr Mcc: Sample Banking, describe the author’s use of evidence, reasoning, and/or stylistic and persuasive elements, and/or feature(s) of the student’s own choosing, but merely asserts rather than explains their importance, or one or more aspects of the response’s analysis are unwarranted based on the text. The response contains little or no support for claim(s) or point(s) made.

The response may lack a clear focus on those features of the text that are most relevant to addressing the task. The response offers an effective analysis of the Page Sample. source text and Excel : Best Paper Printable Free Graph demonstrates an understanding of the analytical task. The response competently evaluates the Cover Page The Letter Sample. Letter author’s use of evidence, reasoning, and/or stylistic and persuasive elements, and/or feature(s) of the student’s own choosing. The response contains relevant and Amazon.com: Fingering Chart (amsco Fingering Charts sufficient support for claim(s) or point(s) made. The response focuses primarily on those features of the text that are most relevant to Business Business, addressing the task. The response offers an insightful analysis of the source text and demonstrates a sophisticated understanding of the analytical task. The response offers a thorough, well-considered evaluation of the author’s use of evidence, reasoning, and/or stylistic and persuasive elements, and/or feature(s) of the student’s own choosing. The response contains relevant, sufficient, and strategically chosen support for claim(s) or point(s) made. The response focuses consistently on those features of the text that are most relevant to addressing the task. Because this category is so important, I've broken it down even further into its two different (but equally important) component parts to make sure everything is as clearly explained as possible.

Critical thinking, also known as critical reasoning, also known as logic, is the skill that SAT essay graders are really looking to see displayed in the essay. You need to Facilitate, be able to evaluate and analyze the claim put forward in the prompt. This is where a lot of students may get tripped up, because they think “oh, well, if I can just write a lot, then I’ll do well.” While there is some truth to the assertion that longer essays tend to Business Letter Cover Page The Letter Sample. Business Letter, score higher, if you don’t display critical thinking you won’t be able to get a top score on your essay. What do I mean by critical thinking? Let's take the previous prompt example: Write an essay in which you explain how Hodgman builds an Changes In Partnership Agreement. The Admission argument to persuade his audience that the hot dog cannot, and never should be, considered a sandwich. An answer to this prompt that does not display critical thinking (and would fall into a 1 or 2 on the rubric) would be something like: The author argues that hot dogs aren’t sandwiches, which is persuasive to the reader. While this does evaluate the prompt (by providing a statement that the author's claim is persuasive to Business Letter The Letter Sample. Letter, the reader), there is no corresponding analysis.

An answer to Facilitate My Meeting, this prompt that displays critical thinking (and would net a higher score on the rubric) could be something like this: The author uses analogies to hammer home his point that hot dogs are not sandwiches. Because the readers will readily believe the first part of the Cover The Letter Business Letter analogy is true, they will be more likely to accept that the Amazon.com: Fingering Chart (amsco Charts second part (that hot dogs aren't sandwiches) is true as well. See the difference? Critical thinking involves reasoning your way through a situation (analysis) as well as making a judgement (evaluation) . On the SAT essay, however, you can’t just stop at abstract critical reasoning - analysis involves one more crucial step. Part II: Examples, Reasons, and Other Evidence (Support) The other piece of the puzzle (apparently this is a tiny puzzle) is making sure you are able to back up your point of view and The Letter Sample. Business Letter critical thinking with concrete evidence . The SAT essay rubric says that the best (that is, 4-scoring) essay uses “ relevant, sufficient, and strategically chosen support for claim(s) or point(s) made. ” This means you can’t just stick to abstract reasoning like this: The author uses analogies to hammer home his point that hot dogs are not sandwiches. Because the readers will readily believe the Sample Services first part of the analogy is true, they will be more likely to accept that the second part (that hot dogs aren't sandwiches) is Business Letter Cover The Letter Sample. true as well.

That explanation is a good starting point, but if you don't back up your point of view with quoted or paraphrased information from the text to support your discussion of the way the Certificate Resume author builds his/her argument, you will not be able to get above a 3 on the Analysis portion of the essay (and possibly the Reading portion as well, if you don't show you've read the passage). Let's take a look of an example of how you might support an interpretation of the author's effect on the reader using facts from the passage : The author’s reference to the Biblical story about Business Letter Page The Letter Sample. Letter, King Solomon elevates the debate about hot dogs from a petty squabble between friends to a life-or-death disagreement. 9+ Turnover Certificate! The reader cannot help but see the parallels between the two situations and thus find themselves agreeing with the Cover The Letter Business author on this point. Does the Certificate | Hostess author's reference to King Solomon actually elevate the debate, causing the reader to Page Sample. Business, agree with the author? From the sentences above, it certainly seems plausible that it might. While your facts do need to be correct, you get a little more leeway with your interpretations of how the author’s persuasive techniques might affect the audience. As long as you can make a convincing argument for the effect a technique the author uses might have on the reader, you’ll be good. Say whaaat?! #tbt by tradlands, used under CC BY 2.0/Cropped and color-adjusted from original. Did I just blow your mind? Read more about the secrets the SAT doesn’t want you to know in Cover Letter ~ Law Resume Cover Short this article.

Your Writing score on the SAT essay is not just a reflection of Business Page Sample. Letter your grasp of the conventions of written English (although it is that as well). You'll also need to be focused, organized, and precise. The response demonstrates little or no cohesion and inadequate skill in the use and control of language. The response may lack a clear central claim or controlling idea. The response lacks a recognizable introduction and conclusion.

The response does not have a discernible progression of ~ Law Firm Resume Cover Linkedin ideas. The response lacks variety in sentence structures; sentence structures may be repetitive. The response demonstrates general and Letter Cover Page Sample. vague word choice; word choice may be poor or inaccurate. The response may lack a formal style and objective tone. The response shows a weak control of the conventions of standard written English and may contain numerous errors that undermine the quality of writing.

The response demonstrates little or no cohesion and limited skill in the use and control of language. The response may lack a clear central claim or controlling idea or may deviate from the Letter ~ Law Resume Cover Short claim or idea over the course of the response. The response may include an ineffective introduction and/or conclusion. The response may demonstrate some progression of ideas within paragraphs but not throughout the response. The response has limited variety in sentence structures; sentence structures may be repetitive. The response demonstrates general or vague word choice; word choice may be repetitive. The response may deviate noticeably from Letter Cover Page Sample. Business Letter a formal style and objective tone. The response shows a limited control of the conventions of Agreement. First: standard written English and contains errors that detract from the quality of writing and may impede understanding. The response is mostly cohesive and demonstrates effective use and control of language.

The response includes a central claim or implicit controlling idea. The response includes an effective introduction and conclusion. The response demonstrates a clear progression of ideas both within paragraphs and throughout the essay. The response has variety in sentence structures. The response demonstrates some precise word choice. The response maintains a formal style and objective tone. The response shows a good control of the conventions of Business Cover Page The Letter Business Letter standard written English and is free of significant errors that detract from the quality of writing. The response is cohesive and demonstrates a highly effective use and command of Letter ~ Law Firm Resume Cover Letter Linkedin language. The response includes a precise central claim.

The response includes a skillful introduction and conclusion. Page The Letter Sample. Letter! The response demonstrates a deliberate and highly effective progression of Format ideas both within paragraphs and throughout the essay. The response has a wide variety in Cover The Letter sentence structures. The response demonstrates a consistent use of Changes Agreement. First: New precise word choice. The response maintains a formal style and objective tone. The response shows a strong command of the conventions of standard written English and is free or virtually free of errors. Because there's a lot of different factors that go into Letter Sample. Letter calculating your Writing score, I've divided the Excel : Best Printable Free Graph discussion of this rubric area into five separate items: One of the Letter Cover Page The Letter Sample. Letter most basic rules of the SAT essay is that you need to express a clear opinion on the assignment (the prompt) . While in school (and everywhere else in life, pretty much) you’re encouraged to take into account all sides of a topic, it behooves you to NOT do this on the SAT essay. Why?

Because you only have 50 minutes to read the passage, analyze the author's argument, and write the essay, there's no way you can discuss every single way in which the author builds his/her argument, every single detail of the passage, or a nuanced argument about My Meeting, what works and what doesn't work. Instead, I recommend focusing your discussion on a few key ways the author is The Letter successful in persuading his/her audience of his/her claim. Let’s go back to the assignment we've been using as an example throughout this article: Write an essay in which you explain how Hodgman builds an argument to persuade his audience that the hot dog cannot, and never should be, considered a sandwich. Your instinct (trained from many years of schooling) might be to answer: There are a variety of 9+ Turnover Certificate Format Resume ways in Business Letter Cover Page The Letter Letter which the author builds his argument. This is a nice, vague statement that leaves you a lot of wiggle room. If you disagree with the author, it's also a way of avoiding having to say that the author is persuasive. Don't fall into this trap!

You do not necessarily have to agree with the author's claim in order to analyze how the author persuades his/her readers that the Photos Of Full Page Grid Free Graph claim is true. Here's an example of Business The Letter a precise central claim about the Mcc: Banking Services example assignment: The author effectively builds his argument that hot dogs are not sandwiches by using logic, allusions to Cover Page The Letter Sample., history and mythology, and factual evidence. In contrast to the vague claim that There are a variety of ways in Nc Dhsr Sample Rfp Investment Services which the author builds his argument, this thesis both specifies what the Page Business Letter author's argument is and the ways in which he builds the argument (that you'll be discussing in the essay). While it's extremely important to make sure your essay has a clear point of Excel : Best Photos Page Printable view, strong critical reasoning, and support for your position, that's not enough to get you a top score. You need to Sample. Letter, make sure that your essay demonstrates a deliberate and highly effective progression of ideas both within paragraphs and throughout the essay. What does this mean? Part of the Amazon.com: Fingering (amsco way you can make sure your essay is well organized has to do with following standard essay construction points. Business Cover Page Business! Don't write your essay in one huge paragraph; instead, include an introduction (with your thesis stating your point of view), body paragraphs (one for each example, usually), and a conclusion. First: The Admission! This structure might seem boring, but it really works to keep your essay organized, and the more clearly organized your essay is, the easier it will be for the essay grader to understand your critical reasoning. The second part of this criteria has to do with keeping your essay focused, making sure it contains a deliberate and highly effective progression of ideas.

You can't just say well, I have an Business Letter Page Sample. Letter introduction, body paragraphs, and a conclusion, so I guess my essay is organized and expect to Mcc: Sample, get a 4/4 on your essay. You need to Letter Page Business Letter, make sure that each paragraph is also organized . Recall the sample prompt: “Write an essay in which you explain how Hodgman builds an Facilitate My Meeting argument to The Letter Sample., persuade his audience that the hot dog cannot, and never should be, considered a sandwich.” And our hypothetical thesis: The author effectively builds his argument that hot dogs are not sandwiches by Facilitate My Meeting, using logic, allusions to Business Cover Page Letter, history and The Admission New mythology, and factual evidence. Let's say that you're writing the paragraph about the author's use of logic to persuade his reader that hot dogs aren't sandwiches. You should NOT just list ways that the author is Cover Sample. logical in support of his claim, then explain why logic in general is an effective persuasive device. While your points might all be valid, your essay would be better served by connecting each instance of logic in the passage with an explanation of how that example of logic persuades the reader to agree with the 9+ Turnover Certificate Format | Hostess author.

Above all, it is Cover The Letter imperative that you make your thesis (your central claim) clear in the opening paragraph of your essay - this helps the grader keep track of your argument. There's no reason you’d want to make following your reasoning more difficult for the person grading your essay (unless you’re cranky and Facilitate My Meeting don’t want to do well on the essay. Business Letter Cover Page Letter! Listen, I don’t want to tell you how to live your life). In your essay, you should use a wide array of 9+ Turnover Certificate vocabulary (and use it correctly). An essay that scores a 4 in Writing on the grading rubric “demonstrates a consistent use of Business Letter The Letter Letter precise word choice.” You’re allowed a few errors, even on a 4-scoring essay, so you can sometimes get away with misusing a word or two.

In general, though, it’s best to 9+ Turnover Certificate Format, stick to using words you are certain you not only know the meaning of, but also know how to Business Letter Cover Sample., use. Amazon.com: Trumpet Fingering Chart! If you’ve been studying up on vocab, make sure you practice using the words you’ve learned in sentences, and Letter Business have those sentences checked by someone who is Letter Firm Resume Cover Short good at writing (in English), before you use those words in an SAT essay. Creating elegant, non-awkward sentences is the Letter Cover Sample. Letter thing I struggle most with under time pressure. For instance, here’s my first try at the previous sentence: “Making sure a sentence structure makes sense is the thing that I have the most problems with when I’m writing in a short amount of time” (hahaha NOPE - way too convoluted and Changes Agreement. First: The Admission Of A New wordy, self). As another example, take a look at these two excerpts from the hypothetical essay discussing how the author persuaded his readers that a hot dog is not a sandwich:

Score of Cover Page The Letter Sample. Business Letter 2: The author makes his point by critiquing the 9+ Turnover Certificate | Hostess argument against him. The author pointed out the logical fallacy of saying a hot dog was a sandwich because it was meat sandwiched between two breads. The author thus persuades the reader his point makes sense to be agreed with and convinces them. The above sentences lack variety in structure (they all begin with the words the author), and the last sentence has serious flaws in Business Letter Cover Sample. Business Letter its structure (it makes no sense). Score of Letter Letter Short 4: The author's rigorous examination of his opponent's position invites the Letter The Letter Sample. Business reader, too, to Nc Dhsr Mcc: Rfp Investment, consider this issue seriously. By laying out his reasoning, step by step, Hodgman makes it easy for the reader to follow along with his train of thought and Business Letter Page Business Letter arrive at the same destination that he has. This destination is Hodgman's claim that a hot dog is not a sandwich. The above sentences demonstrate variety in sentence structure (they don't all begin with the same word and don't have the same underlying structure) that presumably forward the Facilitate My Meeting point of the essay. In general, if you're doing well in all the other Writing areas, your sentence structures will also naturally vary. If you're really worried that your sentences are not varied enough, however, my advice for working on Business Letter Page Sample. Business Letter, demonstrating meaningful variety in sentence structure (without ending up with terribly worded sentences) is Facilitate My Meeting twofold: Read over what you’ve written before you hand it in and change any wordings that seem awkward, clunky, or just plain incorrect.

As you’re doing practice essays, have a friend, family member, or teacher who is good at Letter Cover The Letter Sample. Letter, (English) writing look over 9+ Turnover Certificate Resume, your essays and point out any issues that arise. This part of the Writing grade is all about the nitty gritty details of Letter Cover Page The Letter Business Letter writing: grammar, punctuation, and spelling . 9+ Turnover Resume! It's rare that an Cover The Letter Business Letter essay with serious flaws in this area can score a 4/4 in Reading, Analysis, or Writing, because such persistent errors often interfere with meaning (that is, persistent errors make it difficult for the grader to understand what you're trying to get across). On the Nc Dhsr Sample other hand, if they occur in small quantities, grammar/punctuation/spelling errors are also the things that are most likely to be overlooked. If two essays are otherwise of equal quality, but one writer misspells definitely as definately and Letter Business the other writer fails to Nc Dhsr Mcc: Rfp Investment Banking Services, explain how one of her examples supports her thesis, the first writer will receive a higher essay score. It's only Business Page The Letter Letter when poor grammar, use of Excel : Best Page Grid Printable Graph punctuation, and Letter Page Letter spelling start to Excel : Best Page Paper Printable Free, make it difficult to understand your essay that the graders start penalizing you. My advice for Cover Page Sample. Business working on this rubric area is the same advice as for sentence structure: look over what you’ve written to double check for mistakes, and ask someone who’s good at writing to look over (amsco, your practice essays and point out your errors.

If you're really struggling with spelling, simply typing up your (handwritten) essay into a program like Microsoft Word and running spellcheck can alert you to problems. We've also got a great set of articles up on our blog about SAT Writing questions that may help you better understand any grammatical errors you are making. How Do I Use The SAT Essay Grading Rubric? Now that you understand the Business Letter Cover The Letter SAT essay rubric, how can you use it in your SAT prep? There are a couple of different ways. Use The SAT Essay Rubric To.

Shape Your Essays. Since you know what the SAT is looking for Excel Photos Of Full Page Grid Paper Free in an essay, you can now use that knowledge to guide what you write about in Business Letter Sample. Letter your essays! A tale from my youth: when I was preparing to take the SAT for Photos Of Full Page Grid Graph the first time, I did not really know what the essay was looking for, and assumed that since I was a good writer, I’d be fine. Not true! The most important part of the SAT essay is using specific examples from the passage and Business Letter The Letter Letter explaining how they convince the reader of the author's point. By reading this article and realizing there's more to the essay than being a strong writer, you’re already doing better than high school me. Change the object in that girl’s left hand from a mirror to a textbook and you have a pretty good sketch of what my junior year of high school looked like.

Use The SAT Essay Rubric To. Grade Your Practice Essays. The SAT can’t exactly give you an answer key to the essay. Even when an Nc Dhsr Mcc: Rfp Investment Banking example of an Letter Cover Business essay that scored a particular score is Changes In Partnership Agreement. The Admission Of A provided, that essay will probably use different examples than you did, make different arguments, maybe even argue different interpretations of the text. making it difficult to compare the Business Letter The Letter Sample. Letter two. The SAT essay rubric is the next best thing to an answer key for the essay - use it as a lens through which to Sample Rfp Investment, view and assess your essay. Of course, you don’t have the Letter Business time to become an expert SAT essay grader - that’s not your job. Mcc: Rfp Investment! You just have to apply the rubric as best as you can to your essays and work on fixing your weak areas . For the sentence structure, grammar, usage, and The Letter Business mechanics stuff I highly recommend asking a friend, teacher, or family member who is really good at (English) writing to take a look over your practice essays and point out the mistakes. If you really want custom feedback on your practice essays from experienced essay graders, may I also suggest the PrepScholar test prep platform? I manage the essay grading and so happen to know quite a bit about the essay part of Agreement. First: The Admission Of A New this platform, which gives you both an essay grade and Business Cover The Letter Sample. custom feedback for each essay you complete. Learn more about how it all works here. Are you so excited by Facilitate My Meeting, this article that you want to read even more articles on the SAT essay?

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50 Critical Analysis Paper Topics. VirginiaLynne has been a University English instructor for Letter The Letter over 20 years. She specializes in helping people write essays faster and easier. This type of essay summarizes and evaluates an Cover Firm Cover Linkedin Short, argument, political situation, social phenomenon, historical event, written text, literary work, movie, or performance. Your job writing a critical analysis paper is to: Summarize : You will use your own words to explain clearly what happened. Cover Sample. Business! If it is an event, you will describe the situation, people, and circumstances. If you are dealing with a text or a performance, you will explain the author's thesis, purpose, and audience. Your summary is intended to Nc Dhsr Mcc: Sample Services, help your audience understand this subject clearly and thoroughly.

Analyze: Next, you will explain the meaning of this event, text or performance. You will evaluate what happened and discuss whether it is good, bad or both. If you are discussing a cultural phenomenon or a current event, you can analyze causes and effects or the importance of that event. For a written text or a performance, you will discuss how well the Business Sample. Business Letter, author conveys his or her intentions to the audience. Is the Excel : Best Of Full Grid Graph, author convincing? What are the Letter Cover Page, weaknesses? Respond (sometimes): Often, a critical analysis assignment requires you to present the summary and analysis objectively. However, another way of writing this type of essay is to 9+ Turnover | Hostess, include your own point of view. Business Letter Cover Page The Letter Letter! Be sure to check with your instructor about whether they want you to add your own opinion. If you write this paper with your own personal opinion included, it is sometimes called a summary, analysis, response essay.

Choose a topic from the list below that you find interesting. It helps if you already know something about the situation or the different sides of the issue. What you don't know, you will need to research. If there is a subject you feel strongly about, you will have a better motivation for Letter Firm Letter Linkedin Short doing your essay. However, you will need to be careful to do the summary objectively and to be sure to back up your analysis with clear reasoning, evidence, and argument. 1. Communication differences between men and women . Linguistics professor Deborah Tannen has studied the Business Cover The Letter Letter, way in which men and women communicate differently. Read a summary of the arguments from Format | Hostess her book, Men and Letter The Letter, Women in Conversation . Cover Firm Resume Cover Letter Linkedin! Summarize her argument about the differences between the way men and Cover The Letter Sample. Business Letter, women communicate. Analyze the effectiveness of her suggestions about how we can communicate more effectively. 2. Mcc: Sample Services! Drug use in sports. Pick a sport which has had some problems with steroid use or other illegal enhancements. Summarize the situation.

Analyze what has caused drug use to become an increasing problem. How has this drug use affected the gameplay, the athletes, and/or the fans? 3. Anti-meth campaign. The advertising campaign, The Meth Project, has taken the Say No to Drugs campaigns of the past to new extremes. Analyze the effectiveness of this campaign and/or some of the advertisements. 4. Homelessness. Summarize the situation of the homeless in your community.

What resources are available to help them? Why is homelessness still a problem? You might also want to look at some of the videos on YouTube where homeless people describe their lives. 5. College football . Summarize the Business Letter The Letter Letter, importance of Letter ~ Law Resume Cover Letter, college football for a University. Analyze the Cover Business, effect of football on creating alumni involvement and giving, drawing students to attend the University, and bringing community pride and Excel Photos Of Full Page, economic development. You can also discuss the problems that come with having a football program.

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8. Letter Cover Page The Letter Business Letter! Sports on television. High ticket prices combined with technologically enhanced sports broadcasts and widescreen HD televisions which make you feel you are there, many sports fans prefer to watch the : Best Photos Of Full Page Paper Printable Graph, game at home. Analyze the differences between watching sports live and on TV. Consider how the enhancement of television viewing is changing the sport and how it is played. 9. Multicultural identity. Business Letter Page The Letter Business Letter! We all frequently have to check a box identifying our ethnicity. However, for many people, that choice is 9+ Turnover Format, not easy because they have more than one racial or ethnic group to choose from. Moreover, many people's appearance don't line up with the racial or cultural group they most identify with. Read The Changing Face of America from National Geographic and look at many of the Cover The Letter Sample. Business Letter, faces in the article. Analyze how Americans identify themselves and others by appearances. Why is having a single racial identity so important to Americans?

10. Letter Resume Cover Letter Short! Body size and modeling: Watch the debate between a thin model and Sample. Letter, an obese model below. Summarize the points about women, health and body image. Analyze the arguments for and against using women for models who are outside of the normal, healthy body size. 11. Multicultural families. Adoption and intermarriage between people of different cultures and races has created more families of mixed races and cultures in the United States and other countries. Sample Rfp Investment Banking Services! Describe this situation and analyze how adoption and marriage across racial lines affect individuals in Cover Page The Letter Sample. Letter, those families and the cohesion of the Letter Letter Linkedin, family as a whole. 12.

Changing gender roles: The feminist movement fought to secure equal rights for women. How have the roles of men and women changed over the last 40 years? How have they stayed the Business Page The Letter Letter, same? Analyze the change in gender roles and Nc Dhsr Mcc: Sample Banking Services, whether it has been good or bad for relationships and families. How are these changes seen in cultural images? 13.

Ethnic music: Many mainstream musicians are using ethnic influences from Africa, Latin America and elsewhere in Business Letter Page Business Letter, their work. Describe the Amazon.com: (amsco Fingering, use of ethnic music in one or more artists that you know. Analyze how ethnic or folk music has been used by that artist. 14. Latino influences : As the United States Latino population has grown, Latino culture has become more mainstream. Describe some of the Business Letter Cover The Letter Letter, cultural examples of that Latino influence and analyze how it is changing American culture.

15. Mcc: Sample Rfp Investment Services! Single parent families: The rise in Business Page The Letter, divorce has created many more families headed, at least for a while, by a single parent. Describe the differences between single parent and dual parent families. Analyze the effects of Rfp Investment Banking Services, single parenting on children, on the experience of the parent or on schools and Business Letter Cover Sample. Letter, communities. 1. Explain the changes in a character over the course of a novel . Certificate | Hostess Resume! Analyze the causes and significance of those changes (example: Pip or Estella in Great Expectations ). Letter Cover The Letter Business Letter! 2. Examine a setting in a novel . Explain it in detail.

Analyze the significance of Cover Letter Resume Letter Linkedin Short, that setting, for instance how that setting either foreshadows what is to come, explains a character in the novel, or provides contrast (example: the setting in Jane Eyre ). 3. Explain the conventions of a particular genre such as the Gothic novel, the Realistic novel or the Romance. Analyze how a particular novel meets or subverts those genre expectations. 4. Find out about the background of an author. Examine one of the author's works and analyze how that author's life influenced what they wrote (example: Katherine Mansfield, Virginia Woolf, or Ernest Hemingway). Letter Page Sample. Business Letter! 5. (amsco Charts! Describe the way irony is used in a short story . Analyze how that irony creates meaning. How does using irony work to create meaning in a shorter work? (examples: Flannery O'Connor's short stories, or Mark Twain's). 6. Describe the climax of a work of Letter Page The Letter Business, literature. Analyze how the Changes Agreement. Of A, author builds up to that climax (example: Death of Cover The Letter, Julius Caesar in My Meeting, Shakespeare's play, the trial in To Kill a Mockingbird ). 7. Describe the mood of a literary work . Analyze how the author creates that mood through word choices. 8. Describe a critical dialogue in a play or novel.

Analyze how putting the words in a character's mouth is more effective than just having the author narrate the scene and action in it. 9. Describe the use of Business The Letter Sample. Letter, allegory . Analyze the meaning of the allegory, or analyze why the author chose to Amazon.com: Trumpet Chart (amsco Charts, use allegory in this work (examples: Orwell's Animal Farm or C.S. Business Page Sample. Letter! Lewis's Narnia books or John Bunyan in Pilgrim's Progress ). 10. Look at one scene in a Shakespeare play . Analyze how that scene is crucial to understanding the plot or the development of Sample Rfp Investment Services, a character (example: Ophelia's death in Hamlet ). 11. Describe a static character in a literary work (a character that does not change during the course of the Business Letter Cover Page The Letter Business Letter, work). Analyze why the author chose to use that type of character and how that affects the rest of the work (example: Tiny Tim in Dicken's The Christmas Carol vs. Scrooge). 12. Describe the narrative voice in a work of Chart (amsco Fingering Charts, literature.

Analyze how using that narrative voice impacts the meaning of the work, or how it influences the reader to Business Letter Cover Page Letter, see events in a certain way. This is an Format | Hostess Resume, especially interesting critical analysis to do when a work of literature uses more than one narrative voice (examples: The Help by Cover Page The Letter Kathryn Stockett, Turn of the Screw by Henry James, or Bleak House by Charles Dickens). Sample Banking Services! 13. Examine the historical, cultural or literary context of Business The Letter, a work of literature. Analyze how understanding that context can help the reader understand that work (examples: Chinua Achebe, Things Fall Apart , or Giovanni Boccaccio, Decameron ) 14.

Look at the imagery in a poem or poems by a particular poet. Describe the Nc Dhsr Mcc: Sample Rfp Investment Banking Services, imagery and Cover The Letter Sample. Business, then analyze how it creates meaning, tone and mood (examples: Elizabeth Barrett Brown, Walt Whitman or Carlos Williams). 15. Examine and describe a poem which has a first person point of view . Analyze how telling the poem in the first person allows the Letter ~ Law Letter Linkedin, poet to create meaning (examples: Robert Browning's Fra Lippo Lippi or My Last Duchess). 1. Pick a really terrible movie you have seen . Summarize it and analyze what makes this movie so bad. Is it so badly done that it actually becomes funny to Business Business Letter, watch? (examples: Trolls II , Plan 9 from Outer Space ) 2. Examine a movie based on Changes The Admission New, a book you've read. Analyze how well the book has been adapted into Business Letter The Letter Sample. Business a movie. Format Resume! Explain why you think the director made changes to the book in adapting it for The Letter Sample. Letter the screen. Do the book and the movie have the same impact on the audience? Which is better? (examples: Lord of the My Meeting, Rings , Harry Potter , Hunger Games , The Help ). 3. Evaluate a T.V. series that is based on a novel (or novel series).

Analyze how well the Cover Page Sample., format of T.V. is adapted to telling this particular story (examples: Game of Thrones , BBC Sherlock Holmes, Elementary, Once Upon a Time, The Vampire Diaries ). 4. Look at a T.V. series that is based on true events or real people. Analyze how realistic this depiction is Changes First:, of the Page The Letter Sample. Business Letter, actual lives of the : Best Page Graph, people in the series. Does this series exploit these people? Does being a part of a T.V. show help or hurt them? (examples: Eight is Enough, Breaking Amish, Friday Night Lights ). 5. Examine a movie that is Page Letter, about high school . Analyze whether the Certificate, characters, setting, plot and drama are realistic. Do such movies help people who are struggling in high school?

Do they exploit stereotypes or help to Business Cover Page The Letter Letter, undermine them? (examples: Napoleon Dynamite, 21 Jump street, Mean Girls, Easy A, Project X ) 6. Pick a cake Show. Analyze why these shows are interesting to viewers and how these shows have spawned a new interest in cooking, decorating cakes and other forms of food preparation inside the home. Are these shows really long advertisements for products and Rfp Investment, services? (examples: Cake Boss, Cupcake Wars, and Amazing Wedding Cakes ). 7. Look at a vintage high school movie. Analyze whether the struggles depicted in this movie mirror the Letter Business Letter, one's teens experience today. How are schools, teens, parents, teachers and problems the same or different? (examples: The Breakfast Club, Dead Poet's Society, To Sir With Love, Rebel Without a Cause, Fast Times at Ridgemont High ). 8. Examine a remake of a classic movie. Letter ~ Law! Analyze whether the remake is as good as the original. What has changed? Are some aspects better and others worse? Is the vision of the Cover Page The Letter Sample. Business, directors the Sample, same? (Example: Piranha 3-D, Evil Dead, Red Dawn, Clash of the Titans ). 9. Examine a Hitchcock horror film or another classic horror movie. Cover Page The Letter Sample. Business Letter! Analyze how the movie creates horror and suspense while following the Excel : Best Printable Free Graph, strict Hollywood guidelines of the time (examples: The Birds, Psycho, Vertigo, Rear Window ) 10. Letter Page! Examine a movie based on a comic book series.

Analyze how well the movie interprets the comic book character (examples: The Avengers, Batman, Superman, Captain America, Green Lantern, Ironman ). 11. Examine a Wedding Dress Show. Analyze why these shows are popular. Have they contributed to the sharp rise in wedding costs? Is the popularity related to Mcc: Rfp Investment Banking Services, the fact that so many marriages don't last? (examples: Say Yes to the Dress, My Big Redneck Wedding, My Fair Wedding ). 12. Examine two (or more) movies based on the same comic book character.

Analyze the change in the character over the series, or examine the way two different actors and directors interpreted the character, motivations and Letter The Letter Sample., plot (examples: Spiderman, X-Man, Teenage Mutant Ninja Turtles, Justice League, Superman ). 13. Look at a romantic comedy. Analyze how this genre draws the audience into the story. Trumpet Chart (amsco! What makes a romantic comedy effective? (examples : When Harry Met Sally, Pretty Woman, Clueless, Picture Perfect, Like Crazy ). 14. Choose your favorite horror movie to examine. What makes this such a good horror film? Analyze what elements this movie has that creates the experience of horror in the audience (examples: The Exorcist, Sleepy Hollow, The Silence of the Lambs, The Shining, Halloween ). 15. What makes a good summer movie? Examine one of your favorite summer movies, a classic, or a hit from last summer.

Analyze what makes a movie good for a summer release? What are the audience expectations. How well does this movie match what the audience has come to expect? (examples: Do the Right Thing, Caddyshack, Jaws, (500) Days of Summer ). 16. Pick a dumb comedy. While these sorts of movies don't generally hold up as classic literature, they can make us laugh and be fun to watch with a group of friends. However, there is a fine line between funny dumb and stupid dumb.

Analyze how well your movie presents comedy that is funny for the audience. What makes a movie like this work? (examples: Ted, Bad Santa, The Cable Guy, Borat: Cultural Learnings of America, The Hangover ). Page Sample. Business Letter! 17. Choose a movie that one The Best Picture award. Analyze what makes a movie the best of that year and one of the best of all time. Does your movie have features that most best pictures do? What makes it unique? If it was produced this year, would it win again? (examples: Wings (1927/29-the first Best picture award), Gone With The Wind (1939), Ben Hur (1959), The Sound of Music (1965), Kramer vs. Kramer (1979), The King's Speech (2001). 18. Choose a reality T.V. series : Analyze why people like these shows. Why are they so popular and what makes a reality T.V. show good or bad?

Do these shows exploit the Facilitate My Meeting, people who appear on them? Where should we draw the Business Page Business, line? (examples: Toddlers and Tiaras, Biggest Loser, Survivor ). 19. Cover Letter ~ Law Firm Cover Short! Choose a popular older T.V. sitcom. Research the Business Cover Page The Letter, current events happening at the time the show was produced. Analyze why the show was popular at that time. Did that shows humor last? Can audiences who watch it now still appreciate the humor? (examples: I Love Lucy, Cheers, M.A.S.H ). 20. Examine a popular game show. Explain the history of the show. Analyze how the show works to make the game interesting not only for the contestants but also for the viewing audience.

Was the key ingredient the set-up of the game show, the contestants, the host, the Trumpet Chart Fingering Charts, audience, viewer participation or some other factor? (examples: Let's Make Deal, Minute to Win it, Jeopardy ). How to Write a Visual Analysis Paper. by Letter Cover Page The Letter Letter Virginia Kearney 16. Changes In Partnership First: Of A New! Critical Analysis of Cover Page Sample., Poem The Lake Isle of Innisfree by W.B.Yeats. by Andrew Spacey 0. Parallelism in Writing Sentences with Examples. by Virginia Kearney 9. How to Analyze Literature Using the Changes In Partnership Agreement. The Admission, Post-structuralism School of Criticism. by Lyphen Everyword 5. 100 Cause and Effect Essay Topics. by Virginia Kearney 37. Easy Argumentative Essay Topics for College Students. by Virginia Kearney 5. Business Letter! 100 Problem Solution Essay Topics with Sample Essays. by Virginia Kearney 42. Virginia Kearney 3 years ago from United States. Thanks teaches--I get a lot of my ideas from my discussions with my college students in class and my high school kids at home! Dianna Mendez 3 years ago.

This is a great list for students when selecting an essay topic and critical analysis. Your suggestions are all ones that people find interesting and are popular finds. I will be using this as a reference in classes. Thanks! Virginia Kearney 3 years ago from United States. Thanks so much Ms Dora--I so appreciate that from someone who is Trumpet Fingering Fingering Charts, such a gifted communicator and teacher! Dora Isaac Weithers 3 years ago from The Caribbean. Business Letter Page Business! Very interesting and informative for those still in First: The Admission, the classroom. Good topic ideas from a good teacher. Copyright 2017 HubPages Inc. and respective owners. Other product and company names shown may be trademarks of their respective owners.

HubPages ® is Business Cover The Letter Sample. Business, a registered Service Mark of HubPages, Inc. HubPages and Hubbers (authors) may earn revenue on this page based on affiliate relationships and advertisements with partners including Amazon, Google, and others. Copyright 2017 HubPages Inc. and respective owners.

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Factors influencing the catalytic oxidation of benzyl alcohol using supported phosphine-capped gold nanoparticles† Rohul H. Adnan ab , Gunther G. Andersson c , Matthew I. J. Sample. Business? Polson a , Gregory F. Cover Short? Metha d and Vladimir B. Golovko * ae. a Department of Chemistry, University of Canterbury, Christchurch, 8041, New Zealand. E-mail: [email protected] b Chemistry Department, University of Malaya, Kuala Lumpur, 50603, Malaysia. c Flinders Centre for Nanoscale Science and Technology, Flinders University, Adelaide, SA 5001, Australia. d Department of Business Sample. Business, Chemistry, University of Adelaide, Adelaide, SA 5005, Australia. e The MacDiarmid Institute for Advanced Materials and Nanotechnology, PO Box 600, Wellington, 6140, New Zealand. First published on 20th November 2014. Two phosphine-stabilised gold clusters, Au 101 (PPh 3 ) 21 Cl 5 and Au 9 (PPh 3 ) 8 (NO 3 ) 3 , were deposited and activated on anatase TiO 2 and fumed SiO 2 . These catalysts showed an almost complete oxidation of benzyl alcohol (90%) within 3 hours at 80 °C and Excel Of Full Grid Paper Printable Graph, 3 bar O 2 in methanol with a high substrate-to-metal molar ratio of Business Letter Page The Letter Sample. Letter, 5800 and turn-over frequency of 0.65 s ?1 . Sample Rfp Investment? Factors influencing catalytic activity were investigated, including metal–support interaction, effects of heat treatments, chemical composition of Business Sample., gold clusters, the size of gold nanoparticles and catalytic conditions.

It was found that the anions present in gold clusters play a role in determining the Nc Dhsr Mcc: Rfp Investment, catalytic activity in this reaction, with NO 3 ? diminishing the catalytic activity. High catalytic activity was attributed to the formation of large gold nanoparticles (2 nm) that coincides with partial removal of Business Letter Page The Letter Sample., ligands which occurs during heat treatment and catalysis. Selectivity towards the Amazon.com: Trumpet Fingering Chart (amsco Charts, formation of methyl benzoate can be tuned by selection of the reaction temperature. The catalysts were characterised using transmission electron microscopy, UV-vis diffuse reflectance spectroscopy and X-ray photoelectron spectroscopy. Oxidation reactions, particularly alcohol oxidation, are among the most important and useful reactions used by the chemical industry and academia. 9,10 The most common commercial methods of alcohol oxidation use stoichiometric oxidants, such as chromates, permanganates or peroxides, that often yield a large amount of environmentally dangerous waste. 11 The use of Letter Page Sample. Business Letter, harmful organic solvents ( e.g. chlorinated solvents) may also have a negative environmental impact. 12,13 There is an urgent need to move towards environmentally benign and cost-effective processes involving renewable, environmentally friendly and cheap oxidants, such as molecular oxygen or atmospheric air as opposed to Rfp Investment, peroxides ( e.g. H 2 O 2 and tert -butyl hydroperoxide) 14 with the help of The Letter Sample. Business, suitable catalysts. In recent years, liquid phase oxidation of alcohols has become popular as a model catalytic test, due to simple setup and Fingering (amsco Fingering, handling procedures and relatively mild reaction conditions.

15,16 Supported platinum group catalysts are widely used in Business Letter Page The Letter Business Letter the oxidation of alcohols, yet they often require a secondary metal as a promoter to increase the selectivity and Amazon.com: Trumpet Fingering Charts, stability of such catalysts. 17–21 Hence, gold-based catalysts could be advantageous if such systems would not suffer from the Letter Letter, stability and selectivity issues. 22. A systematic study of the nature of the active sites is crucial in improving the activity and selectivity of Cover Letter ~ Law Letter Short, catalysts towards the formation of the desired partial oxidation products. In the case of Page, heterogeneous Au-based catalysts, the following factors are often considered to define catalytic activity and selectivity: gold particle size and morphology, oxidation state of gold species, metal–support interaction and specific parameters of catalytic testing conditions. The nature of the 9+ Turnover Format | Hostess, active site in the liquid phase oxidation of alcohols is Letter Cover The Letter Business currently still unclear, with both ultra-small particles (2 nm) 23,24 and 9+ Turnover Certificate Resume, larger particles (2 nm) 25 reported as active catalysts. Business Letter Page The Letter Business Letter? Tsukuda et al. reported that as the size of gold nanoparticles reduced below 2 nm, the 9+ Turnover | Hostess, turnover frequency (TOF) for the aerobic oxidation of p -hydroxybenzylalcohol increased significantly. 26 The authors proposed that the Business Page The Letter Business Letter, catalytic activity of these small gold nanoparticles was due to the increased electron density on the gold core and also charge transfer from the poly( N -vinyl-2-pyrrolidone) ligands.

However, Haider et al. observed that smaller size was not necessarily responsible for higher activity – the authors reported that the optimum size of the gold nanoparticles for Facilitate My Meeting, ethanol oxidation is ca. 7 nm, irrespective of the supports. 25 Zheng et al. also observed a similar trend in ethanol oxidation in which the most active catalyst contained gold nanoparticles of around 6 nm. 27 There are currently very few studies on the effects of the Business Letter Cover The Letter Sample. Letter, gold nanoparticle precursor (size, composition etc. ) on My Meeting the performance of resulting catalysts since the Cover Page The Letter Business, majority of reports in the literature are focused predominantly on the morphology and size of gold nanoparticles. 23,28–30 Only recently, several studies on the effects of ligands, such as citrate, polyvinylpyrrolidone and Excel : Best Paper Printable Free, polyvinyl alcohol, on the performance of Business Letter Sample. Letter, gold-based catalysts have been reported in a wide range of Cover ~ Law Firm Resume Linkedin, catalytic reactions – glycerol oxidation, 31 hydrogenation of cinnamaldehyde 32 and reduction of p -nitrophenol. 33 These findings clearly suggest that the nature of ligands plays a critical role in determining the Business Page Sample. Business, performance of the catalytically active gold particles in Excel Photos Of Full Grid Printable Free a particular reaction, perhaps, similarly to the role of support. Business Letter Page The Letter Sample. Letter? 34 Hence, it is important to study the effect of the composition (size of the gold core, neutral organic ligands and anionic ligands or counter-ions) of precursors used in fabrication of gold-based catalysts in order to design catalysts with high activity and improved selectivity. Supported thiol-capped gold clusters have been widely used in Nc Dhsr Mcc: Sample Rfp Investment Services catalytic studies. Business Letter Cover Page Sample. Letter? 35–37 For example, Jin et al. Amazon.com: Trumpet Chart? supported Au 25 (SR) 18 , Au 38 (SR) 24 and Business Page The Letter Business, Au 99 (SPh) 42 clusters on 9+ Turnover Certificate Format Resume various metal oxides and tested them in selective oxidation and hydrogenation reactions. 38–41 Tsukuda et al. Letter Page The Letter Letter? used Au 10 (SG) 10 , Au 18 (SG) 14 , Au 25 (SG) 18 and Au 39 (SG) 24 deposited on hydroxyapatite in styrene oxidation.

42 In contrast, very few studies have focussed on using phosphine-capped gold nanoparticles in catalysis. 23,43–45 Phosphine ligands have weaker bonding interaction between gold and Letter ~ Law Firm Letter Linkedin, phosphorous atoms compared to the gold–sulphur interactions in thiol-capped gold nanoparticles. 46. Building on our recent X-ray spectroscopy studies of supported triphenylphosphine-stabilised gold nanoparticles, 47,48 we hereby aim to study the catalytic performance of materials derived from selected phosphine-capped gold clusters, supported and activated on Cover titania and silica using liquid phase benzyl alcohol oxidation as a model catalytic test. Herein, we prepared two phosphine-capped gold clusters: Au 101 (PPh 3 ) 21 Cl 5 (denoted as Au 101 with mean size of 1.6 ± 0.3 nm) and Au 9 (PPh 3 ) 8 (NO 3 ) 3 (denoted as Au 9 with mean size of 0.8 nm). These clusters were then deposited and activated on TiO 2 (anatase) and SiO 2 (fumed) using sol-immobilisation method; a well-established method used by Rossi, 10 Jin 39 and Hutchings 49 for | Hostess, immobilising pre-synthesized gold nanoparticles or clusters onto supports. The sol-immobilisation method was shown to give minimal aggregation and high dispersion of gold nanoparticles on the supports. 50 The catalysts were then calcined under different atmospheres: oxygen (O 2 ) and The Letter Business, oxygen and Cover Letter Firm Resume Cover, subsequently hydrogen (O 2 –H 2 ) at 200 °C to dislodge the Letter Page Business Letter, phosphine ligands and Chart Fingering Charts, expose the metal core adsorbed on Business Page Business the support to facilitate access by Photos, the substrate. 47.

First, the calculated amount of support (silica or titania) was dried in Business the Schlenk tube under vacuum at 200 °C with stirring overnight (12 h). Upon cooling to room temperature, 5.00 g the support was suspended in dichloromethane (30 mL) using vigorous stirring (750 rpm, magnetic stirrer bar). A solution of calculated amount of Nc Dhsr Services, gold cluster ( e.g. 11.2 mg of Au 101 ) in dichloromethane (10 mL) was added to the suspension of support under vigorous stirring at room temperature and the mixture was left stirring overnight (12 h). The mixture was then dried in vacuum at room temperature and stored at 4 °C (untreated catalysts, labelled as Au x /support-untreated). Two heat treatments were employed in this work: a) calcination under pure O 2 atmosphere at 200 °C for 2 h and b) calcination under pure O 2 at Letter Page Sample. Business 200 °C for 2 h followed by Nc Dhsr Sample Rfp Investment, calcination in Business Letter The Letter Business Letter H 2 at 200 °C for 2 h. 47 All cluster deposition and activation experiments were performed using glassware wrapped in Al foil to avoid exposure of materials to Facilitate My Meeting, light. All prepared catalysts were stored in vials wrapped in Al foil in Business Page The Letter Letter a fridge (4 °C). For the purpose of following discussion catalysts are labelled in the following manner: “ x wt% Au y /support-treatment”, where x corresponds to the weight % of pure Au and Certificate | Hostess Resume, y = 9 or 101.

Product mixtures were analysed using high performance liquid chromatography (HPLC) Dionex Ultimate 300 system equipped with UV detector and fitted with a Luna 5? C18(2) (250 ? 4.60 mm) reversed phase column. The products were eluted using a mixture of 0.05 v/v% trifluoroacetic acid in water (70%) and acetonitrile (30%). Business Letter Letter? Gold content was measured via atomic absorption spectroscopy (AAS) using a Varian SpectraAA 220 FS with ASL hollow cathode lamp for Fingering Chart Fingering, the Au element. A careful heat-treatment was employed in order to remove the capping ligands and expose the gold core to the substrate, yet to minimise aggregation. Here, calcination of the catalysts was done at Letter Page The Letter Business Letter 200 °C under different environments: under pure oxygen (O 2 ) and oxygen followed by hydrogen (O 2 –H 2 ). 28,42 After calcination, the gold clusters aggregated to Excel Photos Page, form larger nanoparticles (Fig. 1 and 2). 47 TiO 2 -based catalysts showed minimal aggregation and narrower particle size distributions as compared to SiO 2 -based catalysts, suggesting that gold formed stronger metal–support interaction with TiO 2 cf. SiO 2 (Fig.

1 and 3). UV-vis DR spectra (Fig. Cover Page Business? 4 and 5) showed the absence of LSPR bands in the cases of untreated catalysts allows us to infer that the gold nanoparticles were predominantly with sizes below 2 nm and retained their non-metallic state. The appearance of an LSPR band in the UV-vis DR spectra of the TiO 2 -supported samples after calcination (Fig. 4 and 5) indicated formation of plasmonic gold nanoparticles which is indicative of the increase in particle size to greater than 2 nm. 55–57 It was previously reported that the position of the maximum of the LSPR band moves to longer wavelength as the size of gold particles increases, although in some cases this general trend broke down due to the effect of the dielectric constant of the surrounding environment. 58–61 Interestingly, the 0.17 wt% Au 101 /TiO 2 catalysts showed aggregation after catalytic reaction (from ca. 2.0 to ca. 3.6 nm; Table 1). Particle size analysis based on the statistical evaluation of numerous TEM images (Table 1) confirms that the increase in particle size after heat-treatments and after catalytic reactions for Au x /TiO 2 catalysts ( x = 9, 101) was consistent with the red shift in Fingering Fingering the peak maxima position of the LSPR bands observed in UV-vis DR spectra. For 0.5 wt% Au 101 /SiO 2 catalyst, a significant agglomeration of gold clusters occurred upon deposition: the gold clusters in the 0.5 wt% Au 101 /SiO 2 -untreated catalyst aggregated to form gold nanoparticles of Letter Sample. Business Letter, mean size 3.6 ± 1.2 nm.

The observed particle size is Format | Hostess Resume almost twice the size of pristine Au 101 cluster and substantially larger than the Letter Cover Sample. Business Letter, size of the gold particles (2.0 ± 0.4 nm) in the case of Au 101 immobilized on TiO 2 at the same surface coverage. The gold cluster also grew non-uniformly to yield a wide particle size distribution with the largest particle found with TEM being ca. 8 nm and Facilitate, the smallest being ca. 2 nm (Fig. 5a and S9a ESI†). After calcination under O 2 and O 2 followed by H 2 at 200 °C, the agglomeration progressed further resulting in the formation of larger gold nanoparticles with wider particle size distributions (Fig. 5(b and c) and S9(b and The Letter Business, c) ESI†). A summary of Facilitate My Meeting, supported gold particle mean sizes and positions of the Business Letter Cover Page The Letter Business Letter, LSPR peak maxima are given in Table 1. Our recent XPS study of phosphine-capped Au clusters on TiO 2 showed that for untreated Au 9 /TiO 2 and Au 101 /TiO 2 a significant fraction of phosphine ligands were dislodged from the gold cores and formed phosphine oxide-like species by interaction with oxygen on Facilitate the TiO 2 surface, leaving a tiny amount of phosphine ligands bound to the gold core. 47 Calcination under O 2 atmosphere detached the majority of phosphine ligands from the gold core by Business Letter Cover The Letter Sample. Letter, forming phosphine-oxide species. It is worth mentioning that while TGA results show the complete removal of phosphine ligands has occurred at 250 °C for the Au 101 clusters (Fig.

S3, ESI†) and at 240 °C for the Au 9 cluster (Fig. S6, ESI†), the phosphine ligands attached to supported Au clusters were not removed as phosphoric acid (H 3 PO 4 ), but as phosphine-oxide species probably due to the interaction with the Letter Firm Resume Short, oxygen from TiO 2 surfaces ( e.g. such oxidized phosphine species remained at the surface of the support). 47 After a combined O 2 –H 2 calcination, phosphine ligands were completely dislodged from the gold core for both Au 9 /TiO 2 and Au 101 /TiO 2 catalysts. Our first XPS study of Business The Letter Letter, a wider range of Facilitate, ultra-small gold phosphine clusters suggests that the nature of the anionic species (Cl ? and NO 3 ? ) did not significantly influence the position of the Au 4f 7/2 peak (84.7 ± 0.1 eV for Au 11 cluster containing Cl ? vs. 85.1 ± 0.1 eV for both Au 8 and Au 9 clusters containing NO 3 ? ) whereas the size of the Business Letter Page The Letter Business, cluster has a more pronounced effect (83.9 ± 0.1 eV for Au 11 cluster containing Cl ? ). 48. The leaching of metal particles into Amazon.com: Fingering Fingering Charts solution is a common problem for metal supported heterogeneous catalysts. However, our phosphine-stabilised Au clusters did not show signs of leaching during our catalytic studies according to Business Cover The Letter, Au loading analysis by AAS (Table S1, ESI†). Secondly, the nature of the support and Mcc: Sample Banking, metal–support interaction dictated the The Letter Sample., performance of the catalysts.

For example, catalysts with similar gold loading on different supports (Table S1, ESI†), Au 101 on anatase (0.13 wt% Au by Page Graph, AAS) showed superior performance (Table 2) when compared with analogous catalyst systems made using fumed-SiO 2 as a support (with 0.18 wt% Au by AAS). Typically, SiO 2 is considered an inert, non-reducible support whereas TiO 2 is an activating, reducible support. 67 The higher catalytic activity of Au/TiO 2 catalysts over Au/SiO 2 was also observed in CO oxidation in many studies. 68–71 Hence, the size effect of gold nanoparticles alone is Business Sample. Letter not sufficient to explain the Cover Letter Resume Linkedin Short, activity of supported gold catalysts. Metal–support interactions (MSI) play crucial role in defining reactivity and Letter Cover Business, selectivity of supported gold catalysts. Haruta et al. and Baiker et al. hypothesized that the oxygen activation occurs at the perimeter ( i.e. interface) of the gold nanoparticles and metal oxide supports.

72–74 This hypothesis could explain the lower activity of 9+ Turnover | Hostess Resume, Au 101 /SiO 2 catalysts as compared to Au 101 /anatase in benzyl alcohol oxidation observed in this study, since silica based catalysts with much larger particles will have much smaller surface area corresponding to the gold–support interface. The high activity of heat treated catalysts can be attributed to stronger metal–support interaction established during calcination. Letter Cover The Letter? Haruta et al. proposed that during calcination gold nanoparticles melted, rearranged and reconstructed themselves to achieve stronger interaction with the TiO 2 support. 75 This hypothesis is in line with the Agreement. Of A New, report by Business Letter Page The Letter Sample. Letter, Buffat and Borel that 2 nm gold nanoparticles melt around 600 K, 76 which is significantly lower than the melting point of the bulk gold (1337 K). Wu et al. : Best Of Full Page Grid Paper Printable? reported that small gold nanoparticles (2–4 nm) sinter at temperature as low as 413 K. Letter Cover Sample. Business? 77 The sintering of gold nanoparticles around 423 K was also reported by Coutts et al. 78 Hence it is experimentally observed that small gold nanoparticles aggregate below the melting point. Analysis of Excel : Best Of Full Paper Graph, supported-gold particle sizes as measured by TEM (Table 1) showed that the particle size distribution of gold nanoparticles was wider (indicated by Business The Letter Letter, larger standard deviation) on SiO 2 support as compared to TiO 2 for the same Au loading (target 0.17 wt%), suggesting that weaker metal–support interaction in Au 101 /SiO 2 catalysts facilitates aggregation resulting in wider particle size distributions despite the significantly higher surface area of Amazon.com: Trumpet Fingering Charts, SiO 2 support. For the same Au loading (0.17 wt%) and support (TiO 2 ), Au 101 cluster-based catalysts showed much higher catalytic activity compared to Letter Cover Page Business, Au 9 -based catalysts even though the gold particles size were smaller in the case of Au 9 /TiO 2 ( cf. Au 101 /TiO 2 analogues, Table 2, entries 19–21 cf. Mcc: Banking Services? entries 4–6). We hypothesize that the presence of anionic species within the gold cluster (Cl ? in Letter The Letter Sample. Au 101 vs.

NO 3 ? in Au 9 ) strongly affect the My Meeting, catalytic activity. From our XPS investigations we have no evidence that the amount and chemical nature of the nitrogen species are changing due to the treatment after the deposition of the Au clusters. To identify the role of the Business Cover Page Sample. Letter, component of the Certificate | Hostess, cluster precursor responsible for quenching of the catalytic activity, we investigated the role of Business Letter Cover The Letter Sample. Business Letter, such an In Partnership Agreement. First: The Admission, anionic component in benzyl alcohol oxidation. Firstly, we added KCl, with the amount according to the weight percentage of Cl ? in Au 101 (PPh 3 ) 21 Cl 5 (0.08 wt%) to Business Cover The Letter Sample. Business Letter, mimic the Nc Dhsr Sample Rfp Investment Banking Services, presence of Cl ? anion, to the catalyst and calcined it under O 2 to Page, resemble Au 101 /TiO 2 –O 2 ; we found no increase in the catalytic activity (Table 2, entry 29 cf. 9+ Turnover Format | Hostess? entry 20). When KNO 3 (amount estimated to mimic the amount of NO 3 ? from Business Letter Cover Sample. Letter, Au 9 , 4.6 wt%) was added to the Au 101 /TiO 2 catalysts, we found noticeable reduction in the catalytic activity (Table 2, entry 28 vs. 8). Facilitate My Meeting? The nitrate is an integral part of the Business Letter Cover Page Sample. Business Letter, Au 9 cluster precursor used in catalyst fabrication and would be perfectly positioned to affect gold particles, causing deactivation of the catalyst (Table 2, entries 19–21). (amsco Charts? For the Au 101 based catalyst (Table 2, entry 28), the nitrate was introduced after the Sample. Business, catalyst had been formed, which could limit the efficiency of the interaction of the nitrate with the gold particles and result in the moderate drop in activity. Hence, it appears that the presence of NO 3 lowers the Letter ~ Law Firm Resume Cover Linkedin, catalytic activity of Au 101 -based catalysts and could be the reason for the significantly lower activity of Business Letter Page Sample. Business Letter, Au 9 -based analogues.

To the best of our knowledge this is the first report of the effect of Facilitate My Meeting, NO 3 ? on activity of gold-based heterogeneous catalysts. While numerous studies report that ultra-small gold nanoparticles (2 nm) are the key active site, 23,26,79 our results demonstrate that the size of gold nanoparticles alone is not sufficient to explain the catalytic activity of catalysts made using phosphine-capped Au nanoparticles as it is considerably affected by the type of anions present in the supported gold cluster catalysts, type of support and activation treatment protocols. Quintanilla et al. investigated the effect of N-based compounds (dodecylamine vs. polyvinylpyrrolidone) as stabilizing agents for gold nanoparticles deposited onto Page Sample. Business ?-Al 2 O 3 in benzyl alcohol oxidation. 80 The authors found that the polyvinylpyrrolidone-capped gold nanoparticles had higher catalytic activity than the dodecylamine-capped gold nanoparticles due to the reduced steric hindrance of the gold surface by the polymer, allowing access of the substrate to the surface of gold nanoparticles. However, in Certificate Format | Hostess our case, the Cover Page Sample. Business, N-based compound is present as a counter anion (NO 3 ? ), not as a stabilizing agent. In summary, we found that catalysts fabricated using a nitrate-containing cluster (Au 9 ) are either inactive or show noticeably lower conversion compared to analogues made using chloride-containing Au 101 , while the addition of extraneous nitrate to the Au 101 -based catalysts diminished their activity. The effect of different calcination conditions is negligible for Au 101 -based catalysts but has significant impact on Trumpet Chart (amsco Au 9 /TiO 2 catalysts (see Table 2). Au 101 /TiO 2 –O 2 and Au 101 /TiO 2 –O 2 –H 2 showed similar catalytic activity and selectivity. However, Au 9 /TiO 2 –O 2 –H 2 showed significantly higher activity as compared to Au 9 /TiO 2 –O 2 and Au 9 /TiO 2 -untreated which were inactive.

This result indicated that heat treatment plays a role in the catalytic activity and selectivity in benzyl alcohol oxidation. Business Letter Page Sample.? Yuan et al. prepared Au 9 /TiO 2 for CO oxidation. 81 The authors observed that untreated Au 9 /TiO 2 catalyst was inactive for CO oxidation while heat treated Au 9 /TiO 2 catalyst under 5% H 2 /Ar was active. My Meeting? However, they did not comment on Letter The Letter Sample. Letter the difference in In Partnership New the catalytic activity of those catalysts. In the case of Au nanoparticles containing residual Cl ? species, calcination under H 2 atmosphere could remove Cl ? in the form of HCl, as proposed by Haruta et al. Business Cover The Letter Sample. Business Letter? 82 However, at Changes In Partnership Agreement. First: New this stage we could not conclude the fate of Business Letter, NO 3 ? species after combined O 2 –H 2 calcination because the available XPS data provide no evidence about how the and nature of the nitrogen species changes after such calcination. The proposed reaction pathway of Changes Of A New, benzyl alcohol oxidation in methanol in the presence of Business, base is Excel Of Full Grid Printable shown in Fig. 6. Benzyl alcohol is Cover Page The Letter Sample. Business first oxidized to Nc Dhsr Rfp Investment Banking Services, benzaldehyde, which serves as an intermediate in this catalytic system. In the presence of base, benzaldehyde is preferentially oxidised further to benzoic acid.

83,84 The formation of methyl ester resulted from the reaction between benzaldehyde and Business Letter Page The Letter Business, methanol (the solvent). We carried out a control reaction using benzaldehyde and benzoic acid as substrates (instead of In Partnership First: The Admission New, benzyl alcohol). When similar conditions (5 bar O 2 , 80 °C, 4 hours) were used for the catalytic oxidation of benzaldehyde (2.5 mmol) in methanol (25 mL) using Au 101 /anatase catalysts, a complete transformation of Cover Business, benzaldehyde to benzoic acid and methyl benzoate with the same distribution of products ( i.e. benzoic acid : methyl benzoate of 70 : 30) was observed. However, we did not observe any reaction when benzoic acid was used as a substrate. Thus, our observations excluded the formation of the methyl ester via the benzoic acid route. For the Au 101 -based catalysts, the catalytic activity arises from formation of the large gold nanoparticles coinciding with removal of PPh 3 ligands.

All untreated Au 101 /TiO 2 (0.01 and Nc Dhsr Sample Services, 0.17 wt%) and Au 101 /SiO 2 (0.17 wt%) that were unable to catalyse benzyl alcohol oxidation, contained sub-2 nm gold nanoparticles. Letter Cover The Letter Letter? In trying to Changes In Partnership Agreement. The Admission Of A, explain this observation one has to consider effects of metal core properties and Business Letter Cover Sample. Business Letter, the possibility that a significant proportion of an otherwise reactive gold surface could be blocked by protective phosphine ligands. Our earlier XPS studies provide evidence of Photos Page Grid Printable, significant loss of protecting PPh 3 ligands during deposition (only ca. 10% of P XPS signal intensity remained, due to residual PPh 3 ligands) in the case of 0.17 wt% Au 101 /TiO 2 . Letter Cover Page The Letter Sample.? 47 Although it is Facilitate My Meeting impossible to outright dismiss the argument that the Letter Page The Letter Sample. Business Letter, residual 10% of ligands could completely deactivate the catalysts, one should attempt to find an alternative explanation. An earlier report by Photos Page Printable Free Graph, Valden et al. demonstrated an important transition from Cover The Letter Sample. Business Letter, non-metallic to Mcc: Banking, metallic properties occurring for ca. Au 300 clusters on Business Sample. Business Letter TiO 2 . 85 Hence, one could hypothesise that sub-2 nm particles (2 nm spherical particles would contain ca. Changes In Partnership Agreement. The Admission New? 250 atoms) 86 could be inactive, as observed in our reactions, due to Page Letter, their non-metallic state. The presence of non-metallic particles in these catalysts is further confirmed by our UV-vis DRS results (Table 1, entries 1 and 14). Nc Dhsr Mcc: Rfp Investment Banking? However, untreated 1.3 wt% Au 101 /TiO 2 (mean gold particle size of 2.7 ± 1.6 nm) and untreated 0.5% Au 101 /SiO 2 (mean gold particle size of 3.6 ± 1.2 nm) gave significant conversions 99% (Table 2, entry 16) and 63%, respectively (Table 2, entry 25) with TOF of the same order of magnitude reflective of the Business The Letter Sample. Letter, metal/substrate ratio.

This observation implies that in the case of My Meeting, highly metal-loaded Au 101 -derived catalysts, the formation of larger, metallic nanoparticles (which is Business Cover Page The Letter Business Letter likely to coincide with even more pronounced loss of phosphine ligands during aggregation) could be responsible for the observed activity. The gold nanoparticles in Excel : Best Of Full Page Grid Printable Graph Au 101 /TiO 2 catalysts agglomerated slightly after the catalytic tests (Table 2). The 31 P NMR spectrum of the reaction mixture showed the presence of triphenylphosphine oxide, which was formed from the phosphine ligands dislodged from the gold core, which then oxidised during the catalytic reaction and Page Sample. Business, dissolved in the catalytic reaction mixture. The Au 101 /TiO 2 -untreated catalyst was active upon recycling ( i.e. in Excel : Best Of Full Grid Free Graph the 2nd consecutive catalytic test) and The Letter Sample. Business Letter, showed noticeably increased conversion (29%, Table 2, entry 10) compared to inactive fresh catalyst, and formed considerable amounts of Trumpet Fingering, benzaldehyde as compared to other catalytic tests in Letter Cover The Letter Business this study (Fig. S11†). Agreement. First: New? Again, the increase in Business Letter Cover The Letter activity of the 0.17 wt% Au 101 /TiO 2 -untreated samples upon recycling could be attributed to an increase in size of the gold nanoparticles and the simultaneous loss of Certificate | Hostess Resume, phosphine ligands from the gold core during the first catalytic test. However, comparison between the Business Cover, two catalysts with very similar ca. 3.5 nm particle sizes – 0.17 wt% Au 101 /TiO 2 recycled (Table 2, entry 10) and activated by Agreement. First: The Admission New, calcination under O 2 (Table 2, entry 5) shows that particle size is clearly not the only factor. It should be emphasized that the Letter Page The Letter Letter, TEM imaging does not allow easy quantification of the density/number of Facilitate My Meeting, Au particles per particle of Letter Sample. Business Letter, support and such TEM-based sizing alone could miss the presence of an inactive population of TEM-invisible smaller particles.

For example, recycled untreated catalyst (Table 2, entry 10) could contain a lower density/number of large gold nanoparticles than calcined catalysts (Table 2, entries 8, 9, 11 and 12). Yet, a possibly more important factor in explaining the observed differences could be the 9+ Turnover Certificate Format | Hostess, effect of the higher-temperature treatment under O 2 atmosphere which could form a better contact between the gold particles and the support, while PPh 3 removal from the gold core is Letter Letter even more pronounced when compared to the recycled catalysts. For example, Haruta et al. suggested the calcination of the as-prepared gold/metal oxide catalysts in an oxidizing atmosphere ( e.g. O 2 ) would form a strong interaction between gold nanoparticles with a metal oxide having an oxygen-enriched surface. 87 Both heat treated Au 101 /TiO 2 catalysts under O 2 and O 2 –H 2 showed no significant loss of catalytic activity and selectivity after the first catalytic test. The evolution of conversion and selectivity of benzyl alcohol oxidation as a function of time is presented in Fig. 7. Cover Cover Linkedin Short? The high conversion of Business Letter Cover Page Sample. Business, benzyl alcohol (80–90%) was observed after the first two to three hours. The selectivity towards the formation of methyl benzoate and benzoic acid are independent of reaction time but primarily dependent on the reaction temperature, as shown in Fig. 8. A considerable amount ( ca. 20%) of benzaldehyde was formed after one hour and then depleted over time (Fig.

7), suggesting that benzaldehyde is the Amazon.com: Fingering Chart (amsco Charts, intermediate in for the formation of benzoic acid and methyl benzoate in Business The Letter Business Letter benzyl alcohol oxidation. 88–90 The effect of the temperature in Cover Letter Firm Cover Letter Linkedin Short this reaction was studied from room temperature (25 °C) up to 80 °C (Fig. 8). Reduction in the temperature of the catalytic reaction results in the reduction of the The Letter Sample. Business, catalytic activity. However, the product selectivity shows non-linear behaviour.

The highest selectivity towards methyl benzoate (93%) was observed at 50 °C with 53% conversion of benzyl alcohol, suggesting the selective formation of methyl benzoate is possible by 9+ Turnover | Hostess Resume, manipulating the reaction temperature.

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essay on murree Pakistan - Murree Hills. A land of Greatest Mountains Colorful Culture - A Complete Guide to Pakistan. Murree is a popular hill station and a summer resort in Pakistan, Murree is specially for the residents of Islamabad. Business Business. Murree is also visited as one of the most favourite destination for Pakistani tourists in Sumer and during snowfall of winter. Murree is located along Islamabad-Kohala highway N75, some 30 km (19 mi) northeast of Islamabad. The name Murree is derived from 'marhi', high place although there is Certificate Resume, a popular belief it was named after the virgin Mary during the British times. It is situated on the southern slopes of the Western Himalayan foothills as they ascend to the northeast towards Kashmir.

During British Rule in the nineteenth century, its altitude was established at 7,000 feet (2,100 m), but its actual altitude has now been determined as 2,300 m (7,500 ft) above sea level. Murree is accessible by road from the Letter Cover Sample. Business Letter centre of the Islamabad and Rawalpindi areas. It is still associated with Britain; many British fruits (including cherries, raspberries and strawberries) thrive locally. There is a church, built in 1857, located at the centre of the town, which is still used as a place of worship. Many houses around the church are still standing, functioning mostly as hotels. Old traditional restaurants have been replaced by fast food shops and newer restaurants. Murree has expanded since 1947 at Cover Letter Resume Cover a rate much greater than that which its infrastructure can sustain. Securing water and electricity has been a constant challenge. Cover. The jam-packed bazaar has caught fire a number of times in the last century, and My Meeting the growth of tourism and a construction boom have had an adverse effect on the local environment. Murree, aftermath of fire in 1875. A 19th century post officeMurree was founded in 1851 by the Governor of Punjab, Sir Henry Lawrence, and was originally established for Business Letter The Letter Business the British troops garrisoned on the Afghan frontier[4] as a sanatorium.

The permanent town of Murree was constructed at Sunnybank in 1853. Certificate Resume. The church was sanctified in May 1857, and the main road, Jinnah Road, formerly known as The Mall (and still commonly referred to as), was built. The most significant commercial establishments, the Letter Cover The Letter Letter Post Office, general merchants with European goods, tailors and a millinery, were established opposite Excel Of Full Page Grid Free Graph, the church. Until 1947, access to Jinnah Road was restricted for natives (non-Europeans). Until 1876, Murree was the summer headquarters of the Punjab local government; after 1876 the headquarters were moved to Simla.[5] The railway connection with Lahore, the capital of the Punjab Province, made Murree a popular resort for Punjab officials, and the villas and other houses erected for Business Cover The Letter Business Letter the accommodation of English families gave it a European aspect. Cover ~ Law Firm Resume Linkedin. It was described in the Gazetteer of Rawalpindi District, 1893–94 as follows: The sanatorium of Business Page Business Letter Murree lied in north latitude 33° 54? 30? and Certificate Format Resume east longitude 73° 26? 30?, at an elevation of 7,517 feet (2,291 m) above sea level, and contained a standing population of 1,768 inhabitants, which was, however, enormously increased during the The Letter Sample. Business [May-November] season by the influx of visitors and their attendant servants and Changes The Admission Of A shopkeepers. It is the most accessible hill station in the Punjab, being distant from Rawalpindi only a five hours' journey by tonga dak. Magnificent views are to be obtained in the spring and autumn of the snow crowned mountains of Kashmir; and Business Letter Cover The Letter Business Letter gorgeous sunset and Resume cloud effects seen daily during the rains [July-August]. Part of the station, especially the Kashmir end, are also well wooded and Letter Cover Page The Letter Business Letter pretty.[4] Murree also can boast of a world-class educational establishment: the *Lawrence School, Ghora Gali.

In 1901 the Cover Letter Resume Cover Short population of the town was officially 1844, although if summer visitors had been included this could have been as high as 10,000. In the hot season it was the headquarters of the Lieutenant General of the Northern Command. The Commissioner of the Rawalpindi Division and the Deputy-Commissioner of Rawalpindi also resided here during part of the hot season, for which period an Assistant Commissioner was placed in Business Letter Cover Page The Letter Sample. Business charge of the 9+ Turnover Certificate Resume subdivision consisting of Murree Tehsil. The site was selected in 1850 almost immediately after the annexation of the Province, and building operations commenced at once. In 1851 temporary accommodation was provided for a detachment of troops; and in 1853 permanent barracks were erected. The garrison generally consisted of three mountain batteries. In 1873, 1874, and 1875 Murree was the summer headquarters of the Punjab Government. It was connected with Rawalpindi town by a service of tongas. The houses crown the summit and sides of an irregular ridge, commanding magnificent views over forest-clad hill-sides into deep valleys studded with villages and cultivated fields. The neighbouring hills were covered during the summer with encampments of British troops, while the station itself is filled with European visitors from the plains and travellers to Kashmir.

A fine view of the snowy peaks of Kashmir is to be had on a clear day, and Cover Sample. Business Letter the crest of Nanga Parbat (26,182 feet (7,980 m)) can sometimes be seen. The municipality was created in Nc Dhsr Mcc: Rfp Investment 1850. The income during the Business Letter Cover The Letter Sample. Business ten years ending 1902–3 averaged Rs. 49,500, and the expenditure Rs. 48,200. Nc Dhsr Sample Banking Services. In 1903–4 the income and expenditure were Rs. 5r,400, chiefly from octroi, and Cover The Letter Sample. Business Letter Rs. In Partnership Agreement. The Admission. 54,400 respectively. The income and expenditure of cantonment funds averaged Rs. 10,000 between 1893 and 1903. The chief educational institutions are the Lawrence Military Asylum for soldiers' children, and the St.

Denys' and Convent English schools for girls. The station contains the Lady Roberts Home for invalid officers and a branch of the Alliance Bank of Simla. The Murree Brewery was the only industrial concern of any importance. Dark and Cloudy Murree Landscape[edit] 1857 War of Independence. See also: 1857 War of Independence in Business Cover Sample. Murree.

In the summer of 1857, the local tribes of Murree and Hazara, including the Dhond Abbasi and Tanoli, planned to attack the British Army. The campaign was led by the chief of the Dhond Abbasi tribe, Sardar Sherbaz Khan, and by Malik Nawab Bahadur Khan of the Tanoli tribe. They fought respectably against the British Army, giving the British considerable difficulties. The British Army eventually signed an agreement with the (amsco Fingering local Abbasi tribe, which was refused by the Tanoli tribe, thereby dividing the opposition to the British. The British Army later ignored the agreement to take control of Murree again. After the British forces' occupation of Murree and Abbottabad, many English soldiers and administrators opted to spend the summers there because of the cooler climate. The British settled in and raised families.

Some prominent people who were born here include: Bruce Bairnsfather - a famous cartoonist during world War I. Francis Younghusband - an army officer and explorer. He established the Bible Society in the Christian High School in Geryal Murree. The society did in depth research into the local languages. This society translated a chapter of new testament book Loqas in Letter Cover Page Sample. Business Dhondi that was noted by the compilers of the Linguistic Survey Of India.[8] Reginald Dyer - officer responsible for the Amritsar Massacre. Bhurban is celebrated as one of the only resort areas of the country where there is Nc Dhsr Mcc: Services, a 5 star hotel built by Letter Cover Business, Pakistan Services Limited, the Pearl Continental Hotel. Amazon.com: Fingering Chart Fingering Charts. Bhurban is Letter Cover Page The Letter Sample., only 9 Kilometers from Murree and Facilitate My Meeting practically it can be called as an area of Murree.

Murre to Nathiagali Nathiagali to Abbottabad (Tour Excursion) Nathiagali the famous resort area is only 45 minutes from Murree. The descent on Letter Letter, the Nathia Gali - Abbottabad road leads to the city of Abbottabad right under the Murree hills. Abbottabad, a popular summer resort in (amsco the midst of spacious valleys, is surrounded by green hills and is a pretty large city and is located at a distance of 116 km from Rawalpindi and Letter Business 217 km from Peshawar if you follow the MAIN road. It can get pretty hot in summers and pretty cold in winters but the temperature range stays bearable. It may feel hot in the sun but its cool in the shade. Surrounded by high hills, Abbottabad is Excel : Best Of Full Paper Free Graph, named after its first British Commissioner Sir James Abbott.

It still has a very British air. The Cantonment area of Abbottabad is still very British. Letter Page The Letter Business. The European bungalows, the club, the (amsco Fingering churches and the cemeteries are still there. Lots of greenery in Abbottabad, beautiful trees and nice gardens. There is a main road which is the centre of activity (I think its called the Mall). The good hotels are SpringField, Sarban and others. Abbottabad is famous for its golf courses.

Take a visit. Also see Shimla Hill View Point, Illayasi Mosque with a natural water spring and there is a pool nearby which I think carries crocodiles. The place has beautiful gardens like; Jinnah Garden, Ladies Garden etc maintained by the local Cantonment Board. The splendid stretch of turf promises plenty of room for Cover The Letter Letter polo, football, hockey and golf. At the back of the Letter ~ Law Firm Resume Short station towards the west is the Brigade Center, which is an ideal place ideal for walks and picnic. Nice place to stay If you're coming from Lahore to Business Letter Page Letter, visit the North. The Nathiagali region serves as home to all kinds of wildlife; various species of birds, insects, butterflies and animals.

Unlike the crows of the southern cities of Agreement. Pakistan, you will find ravens in areas like Nathiagali. Visitors are advised to sun their bedding on arrival to get rid of bed-bugs, and to keep repellants and pesticides for insects as these have a tendency to show up a lot, especially in old homes, and in the monsoon season. Horses are a common sight during summer months and are offered to children and adults alike for rides at rates that are often negotiable. Monkeys are aplenty, previously known to be a little shy, they have reportedly become more aggressive in recent years, some say this due to increased abuse suffered at the hands of tourists, who often tease these monkeys or try to steal them. Business Cover. Monkeys often come up to guesthouses and hotels in search of snacks and can be quite noisy and playful. The World Wildlife Federation has an office in Rfp Investment Banking Services the Galiaath, in recent years, this organisation assisted in the breeding of a certain type of leopard in the Black Forest right by Dungagali and Nathiagali, this area was thought to be a perfect habitat for such creatures, but according to Letter Cover Page Business Letter, local reports they frequently come out of the forest to steal cattle of local villagers.

One such cat had to be shot. Packs of pie-dogs which were previously considered to be a night-time menace can no longer be seen anywhere in the Galiaath, it is thought that most have been killed and consumed by the newly bred leopards. In the summer of 2006, a large number of Certificate | Hostess Resume women were found dead in the deep valleys of Galiath with wounds showing that they were killed, soon, a large leopard was caught which was believed to be the culprit of all cases, he was kept in captivity but was eventually shot as a result of his aggression, his body has been stuffed and Business Sample. kept in the Dhunga Gali Wildlife Museum, the museum owners named him the Ghost of Galiath. These leopards are rarely spotted. However, a pet dog or animal is very likely to be grabbed by the cats at night, and if any such pets are brought to Facilitate My Meeting, Nathiagali they must be kept indoors to Business Letter The Letter Business Letter, avoid this. Thandiani means cold in Resume Letter Short the local language. Letter Cover Page The Letter Business. Its around about 1 hour and 30 minutes on a good decent road. Nc Dhsr Mcc: Banking. Its rises steeply at some places. Page The Letter Business Letter. It is Changes The Admission Of A, 2700 meters above sea level on Business Sample., a small plateau surrounded by pine forests. This beautiful spot can easily be approached from Abbottabad, which is 24 km away. It is totally unspoiled and has the loveliest of views of all the hill stations of Pakistan.

The scenery here is breathtaking and Nc Dhsr Mcc: Banking superb. It is Business Letter Page The Letter Sample., pretty high. Just a few kilometres into Cover Letter Linkedin Short the road and you start gaining height quickly. One place on the road offers a stunning view of Abbottabad city. Thandiani is not located in Business Cover Business the Galliat Range but some other range. Beautiful trees on the way and also a few small caves which are probably home for the wildlife. Thandiani was discovered by the British but was later neglected and 9+ Turnover | Hostess was only rediscovered as a hill station recently so it is The Letter Sample. Business Letter, completely unspoiled. : Best Photos Graph. There are few shops at Thandiani and only one basic guesthouse (no big expectations!). It only gets cold about 2 km before Thandiani.

There is also a Pakistan Television Booster at the top and a Pak Air-Force Radar (No Photographs). But the beauty of this area is its views. Stunning views of all the areas around this region. Business Letter Page Sample. Business. Views of the Galliat Range, Hazara Region, Swat Forests, Chitral region and that of Abbottabad itself. Heard the dawn was beautiful but didn't stay at the guesthouse though. Also heard it gets real cold at night even in Cover Letter Firm Cover Linkedin summers almost below 0 C. Lots of greenery and some beautiful rocks on the ground. There is also a road at Business Business the top which seems to go straight into the sky when you first enter Thandiani but it gives wonderful views. Facilitate. Must visit place! Miran Jani is the highest point in the Galliat Range at Letter Cover Page The Letter Sample. Business Letter about 2867 m. It is First: New, a very scenic trek to Miran Jani Top which offers wonderful views of the pine forests and hills surrounding the region. The trail to Miran Jani is just behind the Page Business Letter Governor's House. Facilitate. You can book horses from Nathia Gali if you dont want to go there by Business Letter Page Sample. Business Letter, foot.

Dungagali is a picturesque small resort situated on the slopes of the Mukshpuri hill (2376 m.). It commands a charming view of a series of wooded spurs projecting towards the Amazon.com: Trumpet Fingering (amsco Fingering Charts river Jhelum on Cover Page The Letter Sample. Business Letter, the western side. From Dungagali one can climb the 2813 m peak of Mukhshpuri, which is the highest point in the range. Natural springs abound on the slopes. Excel : Best Of Full Page Printable Graph. It is 30 km from Murree. There are nice hotels available too. Travel Culture Services (Pvt.) Limited Pakistan. Advertise on this site click for advertising rates. Dubai Travel Culture Offerring Tours, Desert Safaris and hotels in Dubai. Sri-Lanka Tours Our Colombo office operating tours in Sri Lanka. Qatar Travel Culture Tours and Letter Cover Sample. Business travel information about Qatar.

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